Synthesis of epoxides from aldehydes and tosylhydrazone salts catalysed by triphenylarsine: complete trans selectivity for all combinations of coupling partners |
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| Authors: | Aggarwal Varinder K Patel Mamta Studley John |
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| Institution: | School of Chemistry, Bristol University, Cantock's Close, Bristol, UK BS8 1TS. V.aggarwal@bristol.ac.uk |
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| Abstract: | Triphenylarsine catalyses the formation of epoxides from carbonyl compounds and tosylhydrazone salts. This convergent synthesis gives complete trans selectivity for all aldehyde and tosylhydrazone salt coupling partners. |
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