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Dimeric iron n-confused porphyrin complexes
Authors:Hung Chen-Hsiung  Chen Wan-Chin  Lee Gene-Hsiang  Peng Shie-Ming
Institution:Department of Chemistry, National Changhua University of Education, Changhua 50058, Taiwan. chhung@cc.ncue.edu.tw
Abstract:A dimeric iron N-confused porphyrin, Fe(NCTPP)]2 was obtained from the anaerobic reaction of Fe(NCTPP)Br with NaSePh while under aerobic conditions a hydroxo bridged iron dimer with Na bridging the outer-N atoms was obtained and oxygenation occurred on the inner core pyrrolic carbon to form a novel ONCTPP porphyrinic ring.
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