Dimeric iron n-confused porphyrin complexes |
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Authors: | Hung Chen-Hsiung Chen Wan-Chin Lee Gene-Hsiang Peng Shie-Ming |
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Institution: | Department of Chemistry, National Changhua University of Education, Changhua 50058, Taiwan. chhung@cc.ncue.edu.tw |
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Abstract: | A dimeric iron N-confused porphyrin, Fe(NCTPP)]2 was obtained from the anaerobic reaction of Fe(NCTPP)Br with NaSePh while under aerobic conditions a hydroxo bridged iron dimer with Na bridging the outer-N atoms was obtained and oxygenation occurred on the inner core pyrrolic carbon to form a novel ONCTPP porphyrinic ring. |
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