Electronic structure of light-induced lophyl radical derived from a novel hexaarylbiimidazole with pi-conjugated chromophore |
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| Authors: | Kikuchi Azusa Iyoda Tomokazu Abe Jiro |
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| Institution: | Department of Applied Chemistry, Graduate School of Engineering, Tokyo Metropolitan University, 1-1 Minami-Ohsawa, Hachioji, Tokyo 192-0397, Japan. |
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| Abstract: | A novel photochromic hexaarylbiimidazole with a bithienyl group as an extended pi-conjugation unit was synthesized and the light-induced lophyl radical was found to be stabilized due to the delocalization of an unpaired electron, and to strongly absorb near-infrared light. |
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