| Using Natural Cinchona Alkaloids to Promote the Enantioselective Addition of Dialkylzinc to N－Diphenylphosphinylimines |
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| 引用本文： | 张海乐 方春梅 李昕 龚流柱 宓爱巧 崔欣 蒋耀忠. Using Natural Cinchona Alkaloids to Promote the Enantioselective Addition of Dialkylzinc to N－Diphenylphosphinylimines[J]. 中国化学, 2003, 21(7): 955-959. DOI: 10.1002/cjoc.20030210746 |
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| 作者姓名： | 张海乐 方春梅 李昕 龚流柱 宓爱巧 崔欣 蒋耀忠 |
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| 作者单位： | UnionLaboratoryofAsymmetricSynthesis,ChengduInstituteofOrganicChemistry,ChineseAcademyofSciences,Chengdu,Sichuan610041,China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China(No.20102005). |
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| 摘 要： | Cinchona alkaloids are utilized as chiral ligands to promote the enantioselective addition of dialkylzinc to N-diphenyiphosphinylirnlnes affording enantiomerically enriched N-diphenyiphosphinylamines in up to 91% ee.
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| 关 键 词： | 天然化合物 金鸡纳树 生物碱 提取 对映选择加成 二烃基锌 N－二酚氧膦基亚胺 |
Using Natural Cinchona Alkaloids to Promote the Enantioselective Addition of Dialkylzinc to N-Diphenylphosphinylimines |
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| ZHANG,Hai-Le FANG,Chun-Mei LI,Xin GONG,Liu-ZhuMI,Ai-Qiao CUI,Xin JIANG,Yao-ZhongUnion Laboratory of Asymmetric Synthesis,Chengdu Institute of Organic Chemistry,Chinese Academy of Sciences,Chengdu,Sichuan ,China. Using Natural Cinchona Alkaloids to Promote the Enantioselective Addition of Dialkylzinc to N-Diphenylphosphinylimines[J]. Chinese Journal of Chemistry, 2003, 21(7): 955-959. DOI: 10.1002/cjoc.20030210746 |
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| Authors: | ZHANG Hai-Le FANG Chun-Mei LI Xin GONG Liu-ZhuMI Ai-Qiao CUI Xin JIANG Yao-ZhongUnion Laboratory of Asymmetric Synthesis Chengdu Institute of Organic Chemistry Chinese Academy of Sciences Chengdu Sichuan China |
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| Affiliation: | ZHANG,Hai-Le FANG,Chun-Mei LI,Xin GONG,Liu-ZhuMI,Ai-Qiao CUI,Xin JIANG,Yao-ZhongUnion Laboratory of Asymmetric Synthesis,Chengdu Institute of Organic Chemistry,Chinese Academy of Sciences,Chengdu,Sichuan 610041,China |
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| Abstract: | Cinchona alkaloids are utilized as chiral ligands to promote the enantioselective addition of dialkylzinc to N-diphenylphos-phinylimines affording enantiomerically enriched N-diphenyl-phosphinylamines in up to 91% ee. |
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| Keywords: | cinchona alkaloids dialkylzinc N-diphenylphos-phinylimines |
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