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Applications of index matching in reflectometry,SANS and Brewster angle microscopy
Institution:1. Facultad de Ciencias Químicas, Universidad Autónoma de Coahuila, Blvd. V. Carranza y José Cárdenas Valdés, C.P. 25280 Saltillo, Coah., México;2. CINVESTAV IPN-Unidad Saltillo, Industria Metalúrgica 1062, Parque Industrial Saltillo Ramos Arizpe, C.P. 25900 Ramos Arizpe, Coah., México;1. Future Industries Institute, University of South Australia, Mawson Lakes Campus, Mawson Lakes, SA 5095, Australia;2. School of Information Technology and Mathematical Sciences, University of South Australia, Mawson Lakes Campus, Mawson Lakes, SA 5095, Australia;1. São Carlos Institute of Physics, University of São Paulo, SP, Brazil;2. Department of Applied Physics, “Gleb Wataghin” Institute of Physics (IFGW), University of Campinas (UNICAMP), Campinas, SP, Brazil
Abstract:By index matching, we mean, the manipulation of the composition of a material such that heterogeneous regions of a sample present identical refractive indices. Such manipulation is commonly used to exaggerate deviations from bulk properties at the interface between two bulk phases. Whilst index matching is used routinely in small-angle scattering it is in the field of neutron reflection that the technique has only recently been exploited fully. Specific deuteration, either inter- or intramolecular combined with partial structure factor (PSF) analysis has allowed structural detail to be elucidated at resolutions of ∼4 Å. In light scattering Brewster angle microscopy exploits the extinction of ‘p’ polarised light to enhance surface inhomogeneites on the scale of microns.
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