Concerning the existence of linear carbon molecules in soot obtained in an electric arc |
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| Authors: | N. G. Spitsina G. N. Boiko Yu. P. Kudryavtsev V. G. Babaev M. B. Guseva S. E. Evsyukov |
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| Affiliation: | (1) Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka Moscow Region, Russian Federation;(2) Institute of Structural Macrokinetics, Russian Academy of Sciences, 142432 Chernogolovka Moscow Region, Russian Federation;(3) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation;(4) Department of Physics, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation |
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| Abstract: | The presence of soluble linear carbon molecules in fullerene-containing soot obtained by arc spraying of graphite was confirmed by Fourier IR spectroscopy, electron diffraction, mass spectrometry, and NMR spectrometry data. Carbon chains are oriented in the layer perpendicular to the support surface and are packed in a hexagonal crystal lattice with d110 = 4.35 Å.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1387–1390, July, 1995.The present work was supported by the Russian Foundation for Basic Research (Project Nos. 93-03-4492 and 93-03-18705). |
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| Keywords: | linear carbon molecules soot fullerenes electric arc |
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