Reactions of 4-morpholino-1,2-naphthoquinone with enamines ando-phenylenediamine |
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| Authors: | L Yu Ukhin L V Belousova Zh I Orlova O Ya Borbulevych O V Shishkin |
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| Institution: | (1) Institute of Physical and Organic Chemistry, Rostov State University, 194/2 prosp. Stachki, 344090 Rostov-on-Don, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation;(3) Institute for Single Crystals, Ukrainian National Academy of Sciences, 60 prosp. Lenina, 310001 Khar'kov, Ukraine |
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| Abstract: | The reactions of 4-morpholino-1,2-naphthoquinone with enamines, cyclohexanone derivatives, afford 7a-amino-5-morpholinohexahydrobenzob]naphtho1,2]1,4]dioxines, while the reaction witho-phenylenediamine yields 5-morpholinobenzoa]phenazine.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 729–732, April, 2000. |
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| Keywords: | 4-morpholino-1 2-naphthoquinone enamines o-phenylenediamine cycloaddition 7a-amino-5-morpholinohexahydrobenzo[b]naphtho[1 2][1 4]dioxines 7a-hydroxy-5-morpholinohexahydrobenzo[b]naphtho[1 2][1 4]dioxine 5-morpholinobenzo[a]phenazine |
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