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Neue rhodanilatähnliche Verbindungen mit Morpholin |
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| Authors: | Doz. Dr. Ion Gănescu Csaba Várhelyi Gheorghe Brînzan Liviu Boboc |
| Affiliation: | (1) Facultatea de Stiin!["tcedil"]("/content/vp271200133256t3/xlarge355.gif") e, Lehrstuhl für Anorganische Chemie der Universität Craiova, Calea Bucure!["scedil"]("/content/vp271200133256t3/xlarge351.gif") ti 165, Craiova, Rumänien;(2) Babe-Bolyai Universität, Cluj, Rumänien |
| Abstract: | Substitution reactions of K3[Cr(NCS)6] with morpholine were studied. The formula of the complex anion, [Cr(NCS)4(morph)2]–, was established.23 new complex compounds of these types have been prepared from the hydrochlorides of some aliphatic or heterocyclic amines, alkaloids and cobalt(III)ammine bases resp.Their thermal behaviour and the mechanism of pyrolysis of these salts was studied by derivatographic methodes. From UV and IR spectra some structural problems are resolved and discussed. Mit 3 Abbildungen |
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