First total syntheses and spectral data corrections of 11-alpha-methoxycurvularin and 11-beta-methoxycurvularin |
| |
| Authors: | Liang Qiren Sun Yongquan Yu Binxun She Xuegong Pan Xinfu |
| |
| Institution: | Department of Chemistry, State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, People's Republic of China. |
| |
| Abstract: | Concise and efficient total syntheses of 11-alpha-methoxycurvularin and 11-beta-methoxycurvularin were accomplished for the first time. The three-component linchpin coupling and intramolecular acylation reactions were key steps, in which we found the spectral data of 11-alpha-methoxycurvularin and 11-beta-methoxycurvularin, reported in the literature, were reversed with each other. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
