Kinetic regularities in reaction of methanethiol with methanol |
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| Authors: | V. Yu. Mashkin V. R. Grunvald V. N. Yakovleva B. P. Borodin V. I. Nasteka |
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| Affiliation: | (1) Institute of Catalysis, 630090 Novosibirsk, USSR;(2) Volgoural NIPI Gas, Orenburg, USSR |
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| Abstract: | The kinetics of the reaction of methanethiol with methanol has been studied under gradientless conditions. A mechanism is postulated according to which, under the effect of methanol the surface is rapidly methoxylated and then CH3O groups react with methanethiol or methanol to produce dimethyl sulfide and dimethyl ether. The kinetic equations obtained describe fairly well the reaction on the inhomogeneous catalyst surface.
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