| 含异亚丙基聚亚胺醚酮空心微球的制备 |
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| 引用本文： | 王强,常冠军,焦文秀,罗炫,张林,林润雄. 含异亚丙基聚亚胺醚酮空心微球的制备[J]. 化学研究, 2009, 20(2): 22-24 |
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| 作者姓名： | 王强 常冠军 焦文秀 罗炫 张林 林润雄 |
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| 作者单位： | 青岛科技大学,橡塑材料与工程教育部重点实验室,山东,青岛,266042;青岛科技大学,橡塑材料与工程教育部重点实验室,山东,青岛,266042;中国工程物理研究院,激光聚变中心,四川,绵阳,621900;中国工程物理研究院,激光聚变中心,四川,绵阳,621900 |
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| 基金项目： | 国家自然科学联合基金 |
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| 摘 要： | 以1，4-双-（4’-溴苯酰基）苯和2，2-双-[4-（4-氨基苯氧基）苯基]丙烷为单体，以三（二亚苄基丙酮）二钯为催化剂，1，1’-联萘-2，2’-二苯膦（BINAP）为配体，由钯催化的胺基化反应缩聚合成了含异亚丙基的聚亚胺醚酮（pr—PIEK），并通过微封装法制备了pr—PIEK空心微球．
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| 关 键 词： | 聚亚胺醚酮 钯催化 空心微球 |
Preparation of Hollow Microsphere of Poly(arylene imino ether ketone) Containing Isopropylidene Group |
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| WANG Qiang,CHANG Guan-jun,JIAO Wen-xiu,LUO Xuan,ZHANG Lin,LIN Run-xiong. Preparation of Hollow Microsphere of Poly(arylene imino ether ketone) Containing Isopropylidene Group[J]. Chemical Research, 2009, 20(2): 22-24 |
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| Authors: | WANG Qiang CHANG Guan-jun JIAO Wen-xiu LUO Xuan ZHANG Lin LIN Run-xiong |
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| Affiliation: | WANG Qiang, CHANG Guan-jun, JIAO Wen-xiu, LUO Xuan, ZHANG Lin, LIN Run-xiong ( 1. Key Laboratory of Rubber-plastics for Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, Shandong, China; 2. Research Center of Laser Fusion, China Academy of Engiering Physics, Mianyang 621900, Sichuan, China) |
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| Abstract: | Poly(arylene imino ether ketone) containing isopropylidene group(pr-PIEK) was synthesized by the condensation polymerization of 1,4-bis-(4-bromobenzoyl)benzene and 2,2-bis propane via palladium-catalyzed aryl amination reaction.The catalyst system was composed of tris(dibenzylideneacetone)dipalladium and 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl(BINAP).Additionally,the hollow microsphere of pr-PIEK was prepared. |
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| Keywords: | poly(arylene imino ether ketone) palladium-catalyzation hollow microsphere |
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