Synthesis and properties of mono- and bis[2-(dimethylaminomethyl)]cymantrenyl derivatives of ytterbium |
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| Authors: | G. Z. Suleimanov E. A. Zulfugarly E. I. Kazimirchuk V. N. Khandozhko V. N. Kalinin Sh. M. Makhmudov P. V. Petrovskii A. Ya. Usyatinsky V. I. Bregadze I. P. Beletskaya |
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| Affiliation: | (1) Institute of Inorganic and Physical Chemistry, Academy of Sciences of Azerbaidzan, 29 prosp. Narimanova, 370143 Baku, Azerbaidzhan;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation;(3) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation |
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| Abstract: | The reaction of [2-(dimethylaminomethyl)]cymantrenyl]lithium with ytterbium diiodide affords [2-(dimethylaminomethyl)cymantrenyl]ytterbium iodide or bis[2-(dimethylaminomethyl)cymantrenyl]ytterbium depending on the ratio of the starting reactants. Reactions of these complexes with a series of electrophiles (H2O, Me3SiCl, MeCOCl, HgCl2, PhCOCl) were studied and the corresponding derivatives of cymantrene were prepared in high yields.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No.3, pp. 531–533, March, 1994. |
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| Keywords: | [2-(dimethylaminomethyl)cymantrenyl]lithium ytterbium diiodide [2-(dimethylaminomethyl)cymantrenyl]ytterbium iodide bis[2-(dimethylaminomethyl)cy-mantrenyl]ytterbium electrophiles derivatives of cymantrene |
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