Kinetic acidity of aliphatic hydrocarbons. Hydrogen isotope exchange with cesium cyclohexylamide in cyclohexylamine |
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| Authors: | Streitwieser Andrew Keevil Thomas A Taylor David R Dart Edward C |
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| Affiliation: | Department of Chemistry, University of California, Berkeley, California 94720-1460, USA. astreit@berkeley.edu |
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| Abstract: | Kinetic acidities are reported for methane, ethane, propane, cyclopropane, isobutane, neopentane, tetramethylbutane, norbornane, nortricyclene, and adamantane by tritiodeprotonation or deuteriodeprotonation in cyclohexylamine catalyzed by cesium cyclohexylamide. |
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