The electrophoretic effect for the case of electrolyte mixtures |
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| Authors: | J. Quint A. Viallard |
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| Affiliation: | (1) Laboratoire de Thermodynamique et Cinétique Chimique, U.E.R. des Sciences Exactes et Naturelles, Université de Clermont-Ferrand 2, B. P. 45-63170, Aubière, France |
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| Abstract: | The ionic electrophoretic effect for solutions of mixed electrolytes of any type is calculated. The calculation is based on the well-known treatment due to Chen with the same distance of closest approach for all the ions in solution. The improved iterative method used for the relaxation-field treatment is applied. For the latter the electrophoretic velocity results are derived to the second iteration in the perturbation method. |
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| Keywords: | Electrophoretic effect mixed electrolytes Chen effect unsymmetrical electrolytes conductance theory |
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