An efficient synthesis of phthalocyanines based on an unprecedented double-addition of oximes to phthalonitriles |
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| Authors: | Kopylovich Maximilian N Kukushkin Vadim Yu Haukka Matti Luzyanin Konstantin V Pombeiro Armando J L |
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| Institution: | Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001 Lisbon, Portugal. |
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| Abstract: | A novel and efficient method is reported for the preparation of phthalocyanines from phthalonitrile or its derivatives which utilizes low-cost reagents of hydrolytic stability, high simplicity, and easy accessibility, i.e., oximes, and proceeds via an unprecedented double addition of oximes to the nitrile group. |
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