Adjustable structure transition and improved gases (H2, CO2) adsorption property of metal-organic framework MIL-53 by encapsulation of BNHx |
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| Authors: | Si Xiaoliang Zhang Jian Li Fen Jiao Chengli Wang Shuang Liu Shuang Li Zhibao Zhou Huaiying Sun Lixian Xu Fen |
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| Institution: | Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Dalian, P R China. |
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| Abstract: | The structure transition of flexible MOF (MIL-53) can be adjusted by confinement of BNH(x) into MIL-53 channels. Hydrogen and carbon dioxide adsorption properties are also improved by incorporating BNH(x). At 77 K and 1 atm pressure hydrogen storage capacity can reach 2.0 wt% and CO(2) adsorption capacity is 4.5 mmol g(-1) at 273 K 1 atm. |
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