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A novel entry to functionalized benzofurans and indoles via palladium(0)-catalyzed arylative dearomatization of furans
Authors:Yin Biaolin  Cai Congbi  Zeng Guohui  Zhang Ruoqi  Li Xiang  Jiang Huanfeng
Affiliation:School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong, 510640, China. blyin@scut.edu.cn
Abstract:A novel entry to functionalized benzofurans and indoles from furans in moderate to good yields has been developed. This protocol involves palladium(0)-catalyzed dearomatizing intramolecular arylation of the furan ring, formation of a π-allylic palladium complex, furan ring opening, and a β-hydride elimination sequence.
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