Hydrocarbon cool flame-induced transformations of alkali metal chlorides |
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Authors: | M J Pogosyan R K Aliev and A A Mantashyan |
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Institution: | (1) Institute of Chemical Physics, Yerevan, USSR |
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Abstract: | Studies of the effect of stabilized cool flame propane oxidation on alkali metal chlorides have revealed the partial removal of surface chlorine and the formation of alkali and formiate. Formiate formation was tentatively detected by IR spectroscopy. Excess heating (up to 23°C) established on such surfaces in the zone of cool flame compared to untreated ones, can be due to the recombination of surface radicals.
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