Efficient nucleophilic substitution reactions of highly functionalized allyl halides in ionic liquid media |
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| Authors: | SRSSaibabu Kotti Allan D Headley |
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| Institution: | Department of Chemistry and Biochemistry, Texas Tech University, MS 1061 Lubbock, TX 79409-1061, USA |
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| Abstract: | Nucleophilic substitution reactions of highly functionalized allyl halides with three anions, N3−, AcO−, and PhSO2−, in ionic liquid media were conducted. The ionic liquid, Bmim]BF4], was found to be superior to classical organic solvents to give higher yields and faster reaction rates. The resulting products belong to multifunctionalized trisubstituted α,β-unsaturated ketones, which are useful building blocks for organic synthesis. |
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| Keywords: | α β-Unsaturated ketone Ionic liquid SN2 reaction Halides |
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