Synthesis of N-heterocyclic diols by diastereoselective pinacol coupling reactions |
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| Authors: | Sandeep Handa Manpreet S Kachala Sarah R Lowe |
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| Institution: | Department of Chemistry, University of Leicester, Leicester LE1 7RH, UK |
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| Abstract: | A series of 5-8 membered N-heterocyclic diols have been prepared from acyclic dicarbonyls via diastereoselective pinacol reactions whereby cis- or trans-diol stereoselectivity is controlled by the choice of low-valent metal reagent used. |
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| Keywords: | Pinacol couplings N-Heterocycles Diols |
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