Selective reduction of aromatic azides with hexamethyldisilathiane: synthesis of new 2-azidopyrrolo[2,1-c][1,4]benzodiazepines |
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| Authors: | Ahmed Kamal K.Laxma Reddy |
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| Affiliation: | Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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| Abstract: | 2-Azidopyrrolobenzodiazepines have been synthesized via cyclization of ω-azidocarbonyl compounds employing hexamethyldisilathiane by selectively reducing the aryl azido functionality. |
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| Keywords: | Pyrrolobenzodiazepines Reductive cyclization Antitumour agents |
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