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Hetero-calix[4]pyrroles: incorporation of furans, thiophenes, thiazoles or fluorenes as a part of the macrocycle
Authors:Mi-Young Song  En-Young Kim  Kyung Il Kim  Hong-Seok Kim  Chang-Hee Lee
Institution:a Department of Chemistry, Kangwon National University, Chun-Chon 200-701, South Korea
b Department of Industrial Chemistry, Kyungpook National University, Dae-Gu 702-701, South Korea
Abstract:Furans, thiazoles, fluorene or thiophene incorporated calix4]pyrrole analogues were synthesized and characterized. The synthesis was achieved by utilization of various building blocks such as 7, 13, 14, 18 and 21. Acid catalyzed condensation of those building blocks with acetone or meso-disubstituted dipyrromethanes afforded desired macrocycles.
Keywords:Calix[4]pyrrole  Hetero-calix[4]pyrroles  Anion binding  H-Bonding  Modified calixpyrrole  Dithiazolyl methane  Fluorenone
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