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Investigation of the Montmorillonite clay-catalyzed [1,3] shift reaction of 3-methyl-2-butenyl phenyl ether
Authors:Matthew R. Dintzner  Kara M. Morse  Kristen M. McClelland  Deborah M. Coligado
Affiliation:Department of Chemistry, DePaul University, 1036 West Belden Ave., Chicago, IL 60614, USA
Abstract:The [1,3] shift reaction of 3-methyl-2-butenyl phenyl ether was catalyzed more effectively by Montmorillonite K10 clay than Montmorillonite KSF clay, and proceeded with greatest ortho-selectivity in carbon tetrachloride at room temperature.
Keywords:prenylation   phenols   Montmorillonite clay   [1,3] shift reaction   allyl phenyl ethers
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