Synthesis and chiroptical properties of two new planar-chiral macrocycles |
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| Authors: | Piotr Pi?tek Janusz Jurczak |
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| Affiliation: | a Department of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warsaw, Poland
b Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland |
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| Abstract: | Could simple intraannular-arm macrocyclic systems exist in enantiopure stable forms? The effective synthesis of two representative compounds of such a class, their resolution into enantiomers, and experiments justifying their stability toward racemization are presented. |
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| Keywords: | Macrocycles Planar chirality Chiroptical properties Synthesis |
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