Towards an enantiospecific total synthesis of garsubellin A and related phloroglucin natural products: the α-pinene approach |
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| Authors: | Goverdhan Mehta Mrinal K Bera |
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| Institution: | Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India |
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| Abstract: | The first enantiospecific approach to garsubellin A and related phloroglucin natural product nemorosone, of contemporary interest from (−)-α-pinene, has been delineated. Through a series of stereospecific operations, the requisite stereochemistry of the prenyl groups has been secured. Kende cyclization has been employed as the key step to construct the functionalized bicyclo3.3.1]nonane core. |
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