Chemo- and regioselective reduction of nitroarenes, carbonyls and azo dyes over nickel-incorporated hexagonal mesoporous aluminophosphate molecular sieves |
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| Authors: | Parasuraman Selvam Susanta K Mohapatra Radha V Jayaram |
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| Affiliation: | a Department of Chemistry, Indian Institute of Technology--Bombay, Powai, Mumbai 400076, India
b Applied Chemistry Division, University of Mumbai, Institute of Chemical Technology, Matunga, Mumbai 400019, India |
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| Abstract: | Nickel-incorporated hexagonal mesoporous aluminophosphate (NiHMA) molecular sieves were found to be highly efficient heterogeneous catalysts for the chemo- and regioselective reduction of nitroarenes and carbonyl compounds as well as the reductive cleavage of azo functions, including bulkier substrates, by the hydrogen transfer method. |
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| Keywords: | Catalytic transfer hydrogenation Nitro compounds Carbonyl compounds Mesoporous molecular sieves Nickel |
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