Direct allylic substitution of allyl alcohols by carbon pronucleophiles in the presence of a palladium/carboxylic acid catalyst under neat conditions |
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| Authors: | Nitin T. Patil |
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| Affiliation: | Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan |
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| Abstract: | The reaction of allylic alcohols with carbon pronucleophiles in the presence of the Pd(PPh3)4/carboxylic acid combined catalytic system, under neat conditions (without an organic solvent or without water as the solvent) enabled the direct allylation of the pronucleophiles, giving the corresponding allylated products in high yields. |
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| Keywords: | Palladium catalyst Allylic substitution π-Allylpalladium complex Pronucleophile Water Palladium carboxylic acid catalyst Allylic alcohol |
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