Synthesis of the BCD ring system of azaspiracid: construction of the trispiro ring structure by the thioether approach |
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| Authors: | Yuichi Ishikawa |
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| Affiliation: | Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, Yokohama 223-8522, Japan |
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| Abstract: | The synthesis of the BCD ring system of azaspiracid 1 has been attained. Construction of the stereochemistry of the C13 position was successfully controlled by connection between the B ring and the C ring with a sulfur atom. |
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| Keywords: | Mytilus edulis Marine polyether azaspiracid trispiro ring |
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