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Synthesis of cyclic hydrazines by ring-closing metathesis of dienes and enynes tethered by an N-N bond
Authors:Jinsung Tae  Dong-Woo Hahn
Institution:Center for Bioactive Molecular Hybrids (CBMH) and Department of Chemistry, Yonsei University, 134 Shinchon-Dong, Seodaemum-Ku, Seoul 120-749, South Korea
Abstract:Ring-closing metathesis of dienes and enynes tethered by an N-N bond produced 6- to 10-membered cyclic 1,2-diaza compounds. The enyne RCM adducts were further transformed by Diels-Alder reaction into aromatic compounds.
Keywords:Cyclizations  Cyclic hydrazines  Diels-Alder reaction  Ring-closing metathesis  Ruthenium
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