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Radical deoxygenation of tertiary alcohols via trifluoroacetates |
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| Authors: | Joong-Gon Kim Doo Ok Jang |
| Affiliation: | a Department of Chemistry, Yonsei University, Wonju 220-710, South Korea b Center for Bioactive Molecular Hybrids, Yonsei University, Seoul 120-749, South Korea c Biotechnology Division, Hanwha Chemical R&D Center, Daejeon 305-345, South Korea |
| Abstract: | Trifluoroacetates of tertiary alcohols undergo deoxygenation by Ph2SiH2 in the presence of (tBuO)2 in excellent yields of the deoxy products without affecting the stereochemistry at β-carbon. |
| Keywords: | Radical tert-Alcohol Deoxygenation Trifluoroacetate |
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