Iodination of organotrifluoroborates: synthesis of vinyl and alkynyl iodides |
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| Authors: | George W Kabalka Arjun Reddy Mereddy |
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| Institution: | Departments of Chemistry and Radiology, The University of Tennessee, Rm 612 BuehlerDabney Hall, Knoxville, TN 37996-1600, USA |
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| Abstract: | Vinyl- and alkynyltrifluoroborates are rapidly converted to vinyl and alkynyl iodides under mild conditions using sodium iodide in the presence of chloramine-T. The reaction is stereospecific and proceeds in excellent yield. |
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| Keywords: | Iodination Organotrifluoroborates Vinyl iodides Alkynyl iodides |
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