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Synthesis of aromatic hyperbranched PAMAM polymers
Authors:Lance J Twyman  Amy SH King  John Burnett  IanK Martin
Institution:The Department of Chemistry, Sheffield University, Sheffield S3 7HF, UK
Abstract:Our preliminary results towards the synthesis of hyperbranched polyamidoamine (PAMAM) polymers as ‘dendrimer equivalents’ is described. An aromatic AB2 bis-amino acid monomer was polymerised at 165 °C (under vacuum) and the crude mixture purified by dialysis. Analysis by GPC and MALDI-TOF mass spectroscopy showed that the purified hyperbranched polymers possessed an Mn of 2000 and a PD of 3.2.
Keywords:Hyperbranched polymers and dendrimers
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