Efficient trapping of the intermediates in the photooxygenation of sulfides by aryl selenides and selenoxides |
| |
| Authors: | Nikoletta Sofikiti |
| |
| Institution: | Department of Chemistry, University of Crete, 71409 Iraklion, Greece |
| |
| Abstract: | Aryl selenides and selenoxides trap efficiently the intermediates in the reaction of singlet oxygen with sulfides. In the co-photooxygenation of 1 equiv of an aryl selenoxide with 1.3 equiv of dimethyl sulfide, the aryl selenone is formed quantitatively. Aryl selenides require 4-5 equiv of sulfide for their complete co-oxidation to selenones. |
| |
| Keywords: | Singlet oxygen Selenium and compounds Sulfides Oxidation |
| 本文献已被 ScienceDirect 等数据库收录！ |
