2-Iodoxybenzenesulfamides: new pseudobenziodoxole-based hypervalent iodine reagents |
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| Authors: | Alexey Y Koposov |
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| Institution: | Department of Chemistry, University of Minnesota Duluth, Duluth, MN 55812, USA |
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| Abstract: | Amides of 2-iodoxybenzenesulfonic acid were prepared by the dioxirane oxidation of the corresponding 2-iodobenzenesulfamides and isolated as stable, microcrystalline products. These new representatives of the pseudocyclic hypervalent iodine compounds can selectively oxidize benzylic alcohols to aldehydes. |
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| Keywords: | Hypervalent iodine Oxidation Benziodoxole IBX |
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