Iridodials: enantiospecific synthesis and stereochemical assignment of the pheromone for the golden-eyed lacewing, Chrysopa oculata |
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Authors: | Kamlesh R. Chauhan Qing-He Zhang Jeffrey R. Aldrich |
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Affiliation: | a USDA-ARS Chemicals Affecting Insect Behavior Laboratory, B-007, BARC-West, Beltsville, MD 20705, USA b Department of Entomology, University of Maryland, College Park, MD 20742, USA |
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Abstract: | 1R,2S,5R,8R; 1R,2S,5R,8S; 1S,2S,5R,8R; and 1S,2S,5R,8S-Iridodials have been prepared in five steps from 4aS,7S,7aR and 4aS,7S,7aS-nepetalactones, major components of catnip oil. 1R,2S,5R,8R-Iridodial has been identified as a male-produced male-aggregation pheromone for Chrysopa oculata, the first pheromone of any kind identified for lacewings. |
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Keywords: | Iridodials Nepetalactone Lacewing |
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