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Green oxidations. The use of potassium permanganate supported on manganese dioxide
Authors:Ahmad Shaabani  Peiman Mirzaei  Donald G Lee
Institution:a Department of Chemistry, Shahid Beheshti University, PO Box 19839-4716, Tehran, Iran
b Department of Chemistry and Biochemistry, University of Regina, SK, Canada S4S 0A2
Abstract:Permanganate supported on active manganese dioxide can be used effectively for the oxidation of organic compounds under heterogeneous or solvent-free conditions. The residue that remains after extraction of the organic products, manganese dioxide, can be recycled, making the process infinitely sustainable, in theory. The use of this approach for the oxidation of arenes, alcohols and sulfides is described.
Keywords:Manganese dioxide  Potassium permanganate  Solid support  Arenes
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