Probing the formation and chemistry of enoxyoxirane derivatives in the C-ring en route to guanacastepene |
| |
| Authors: | Mihirbaran Mandal |
| |
| Affiliation: | a Laboratory for Bioorganic Chemistry, Sloan-Kettering Institute for Cancer Research, 1275 York Ave, New York, NY 10021, USA
b Department of Chemistry, Columbia University, Havemeyer Hall 3000 Broadway, New York, NY 10027, USA |
| |
| Abstract: | Enol acetate and silyl enol ether, derivatives of 2 and 3 undergo stereoselective epoxidation from the β-face of the C13-C14 olefin. The progression of these compounds to the C13 acetoxy C14 ketones is described. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
