Investigation of the behavior of arenediazonium salts with olefins in BmimPF6 |
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| Authors: | George W. Kabalka Gang Dong Bollu Venkataiah |
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| Affiliation: | Departments of Chemistry and Radiology, The University of Tennessee, Knoxville, TN 37996-1600, USA |
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| Abstract: | The palladium-catalyzed reactions of olefins with arenediazonium salts in ionic liquids were investigated. For methyl acrylate and methyl acrylonitrile, normal Heck cross-coupling products are obtained in good yields. However, highly selective dimerization products are formed in excellent yields for styrenes. The catalyst system can be recycled. |
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| Keywords: | Ionic liquids Diazonium salts Heck reaction Dimerization Palladium catalyzed |
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