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A novel conversion of erythro phospholane epoxides to one-carbon atom homologated allylic alcohols |
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| Authors: | Valluru Krishna Reddy Tatsuo Oshikawa |
| Institution: | a Satellite Venture Business Laboratory, Shizuoka University, Hamamatsu 432-8561, Japan b Department of Materials Chemistry, Faculty of Engineering, Shizuoka University, Hamamatsu 432-8561, Japan c Department of Chemistry and Biochemistry, Numazu College of Technology (NCT), Numazu 410-8501, Japan |
| Abstract: | A novel synthetic approach is described to incorporate one more carbon atom at C-2 position of phospholane oxides as homologated allylic alcohol by treatment of erythro-2,3-epoxy-3-methylphospholane 1-oxides with excess of dimethylsulfonium methylide. |
| Keywords: | Dimethylsulfonium methylide Epoxide homologation Phospha sugars Hetero sugars |
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