Chiral [2.2.2] dienes as ligands for Rh(I) in conjugate additions of boronic acids to a wide range of acceptors |
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Authors: | Defieber Christian Paquin Jean-François Serna Sonia Carreira Erick M |
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Institution: | Laboratorium für Organische Chemie, ETH H?nggerberg, HCI H335, 8093 Zürich, Switzerland. |
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Abstract: | reaction: see text] We document a series of investigations that led to new substituted 2.2.2]-diene ligands which display high selectivity in Rh(I)-catalyzed conjugate addition reactions to substrates not previously examined with diene ligands. Moreover, we disclose an unexpected, interesting effect that results from the introduction of a third C=C onto the ligand scaffold (cf. 1). |
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