Synthesis and Characterization of Solid Coordination Complexes of Diamides for Uranium(VI) and Thorium(IV) |
| |
| Authors: | You-Shao Wang Ai-Ping Yang Ge-Fei Zhou Xu-Fang Tan |
| |
| Affiliation: | (1) Laiyang Agricultural College, Laiyang, 265200 Shandong Province, P.R. China |
| |
| Abstract: | Five kinds of solid coordination complexes of uranium(VI) and thorium(IV) with the diamide (N,N,N ,N-tetrabutylmalon-amide (TBMA), N,N,N,N-tetrabutylsuccinylamide (TBSA), N,N,N,N-tetrabutylglutaramide (TBGA), N,N,N,N-tetrabutyl-adipicamide (TBAA)) were synthesized. All these complexes of UO2(NO3)2·TBMA, UO2(NO3)2· TBSA, [UO2(NO3)2·(TBGA1/2)2]x, UO2(NO3)2·TBAA and Th(NO3)4·2TBMA were characterized by elemental analysis, UV spectra, IR spectra and 13C NMR spectra. The coordination form and proposed structures of the complexes are also discussed. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
