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| Stereoselective Synthesis of (+)-△~5-Dehydrosugiyl Methyl Ether | |
| 作者姓名： | An Pai LI Xiao Shui PENG Yong Hong GAN Xin Fu PAN* Department of Chemistry National Laboratory of Applied Organic Chemistry Lanzhou University Lanzhou 730000 |
| 作者单位： | An Pai LI，Xiao Shui PENG，Yong Hong GAN，Xin Fu PAN* Department of Chemistry，National Laboratory of Applied Organic Chemistry，Lanzhou University，Lanzhou 730000 |
| 基金项目： | the National Natural Science Foundation of China (No. 29372050) for financial support. |
| 摘 要： | Most diterpenoids exhibit significant bioactivities1-4. (5-Dehydrosugiyl methyl ether was separated from Taxodium distichum Rich which showed significant bioactivity against KB5, and assigned the structure 1. This compound was obtained by Takashi MATSUMOTO from (+)-dehydroabietic acid with a known procedure6, but the synthetic route is too long. In order to study the relationship between the structure and bioactivities. The certain diterpene synthesis has been extended in our laboratory7… |
| 关 键 词： | synthesis diterpenoids geranic (+)-△~5-dehydrosugiyl methyl ether. |
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