柔性ZnNi/Al-LDHs/碳纤维复合材料的制备及光-电催化特性 |
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引用本文: | 田晶晶,陈涛,包星辰,高梦旭,于业笑,彭思遥,晋冠平. 柔性ZnNi/Al-LDHs/碳纤维复合材料的制备及光-电催化特性[J]. 电化学, 2018, 24(4): 392. DOI: 10.13208/j.electrochem.170726 |
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作者姓名: | 田晶晶 陈涛 包星辰 高梦旭 于业笑 彭思遥 晋冠平 |
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作者单位: | 合肥工业大学化学化工学院,合肥可控化学反应及材料化工重点实验室,安徽 合肥 230009 |
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基金项目: | 国家自然科学基金(NSFC, No. U140710231)和国家级大学生创新训练计划项目 (No. 201710359028). |
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摘 要: | 本文采用电化学方法,制备了一种便于回收和分离的柔性锌镍/铝层状双羟基/碳纤维(ZnNi/Al-LDHs/CFs) 复合材料. 采用X 射线衍射、红外光谱、场发射扫描电镜、电感耦合等离子体原子发射光谱和电化学阻抗光谱技术表征了ZnNi/Al-LDHs/CFs 复合材料的结构、形貌和光电催化性能. 与单独使用Zn/Al-LDHs/CFs 作为光催化剂或Ni/Al-LDHs/CFs 作为电催化剂相比较,ZnNi/Al-LDHs/CFs 复合材料显示了良好的光-电双功能催化特性,既可被用作乙醇和甲醇氧化的电催化剂,也可光电协同催化 2,6-二氯苯酚降解.
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关 键 词: | 电化学制备 柔性碳纤维复合材料 锌镍/铝层状双羟基/碳纤维 光电双功能催化剂 |
收稿时间: | 2017-07-27 |
Electrochemical Preparation andPhoto-Electro Catalytic Properties of Flexible ZnNi/Al-LDHs/Carbon Fibers Composite |
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Abstract: | In this work, a promising flexible composite consisting of zinc (Zn), nickel (Ni) and aluminum (Al) layered double hydroxide coated carbon fibers (ZnNi/Al-LDHs/CFs) was prepared by electrochemical method with convenient recovery and separation. The structures, morphologies, and photo-electro catalytic properties of ZnNi/Al-LDHs/CFs were characterized by X-ray diffraction, infrared spectroscopy, field emission scanning electron microscopy, inductively coupled plasma atomic emission spectrometry and electrochemical impedance spectroscopy techniques. The excellent photo-electro bifunctional catalytic properties were obtained with the ZnNi/Al-LDHs/CFs composite as compared to that of Zn/Al-LDHs/CFs (photo catalyst) or Ni/Al-LDHs/CFs (electrocatalyst) alone, which could be used in the electro-catalytic oxidations of methanol and ethanol, as well as the photo-electro synergistically catalytic degradation of 2,6-dichlorophenol. |
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Keywords: | electrochemical preparation flexible carbon fibers composite ZnNi/Al-LDHs photo-electro double catalyst |
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