Kinetic resolution of 1-O-alkylglycerols by lipase |
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Affiliation: | 1. Institute of Pharmacy, Biochemical Pharmacy, Martin Luther University (MLU) Halle-Wittenberg, Wolfgang-Langenbeck-Str. 4, 06120 Halle (Saale), Germany;2. Department of Pharmaceutical Technology and Biopharmaceutics, Philipps University Marburg, Ketzerbach 63, 35037 Marburg, Germany;3. Centre for Innovation Competence – HALOmem, MLU Halle-Wittenberg, Kurt-Mothes-Str. 3, 06120 Halle (Saale), Germany;4. Max Planck Institute of Colloids and Interfaces, Am Mühlenberg 1, 14476 Potsdam, Germany;5. Martin Luther University Halle-Wittenberg, Center for Structure and Dynamics of Proteins (MZP), Weinbergweg 22, 06120 Halle (Saale), Germany;6. Institute of Pharmacy, Biomedical Materials Group, MLU Halle-Wittenberg, Heinrich-Damerow-Str. 4, 06120 Halle (Saale), Germany;1. Institute of Process Engineering (IPE), ETH Zurich, Sonneggstrasse 3, 8092 Zurich, Switzerland;2. RMS Foundation, Bischmattstrasse 12, 2544 Bettlach, Switzerland;1. Chemistry Department, Faculty of Science, Fayoum University, Fayoum City, Egypt;2. Chemistry Department, Al-Quwayiyah College of Science and Humanities, Shaqra University, Kingdom of Saudi Arabia;3. Cyclotron Project, Nuclear Research Center, Egyptian Atomic Energy Authority, P.O. 13759, Cairo, Egypt;4. Hot Laboratories Center, Egyptian Atomic Energy Authority, P.O. 13759, Cairo, Egypt;5. Chemistry Department, Faculty of Science, Ain–Shams University, Cairo, Egypt;1. School of Chemical Eng., National Technical Univ. of Athens, Heroon Polytechniou 9, Athens 15780, Greece;2. Institute of Nanoscience and Nanotechnology, National Center for Scientific Research “Demikritos”, Patr. Gregoriou E & 27 Neapoleos Str., Agia Paraskevi, Athens 15341, Greece;1. Dipartimento di Scienze e Ingegneria della Materia, dell’Ambiente ed Urbanistica (SIMAU), Facoltà di Ingegneria, Università Politecnica delle Marche, Via Brecce Bianche, 60131 Ancona, Italy;2. Dipartimento di Ingegneria Industriale e Scienze Matematiche (DIISM), Facoltà di Ingegneria, Università Politecnica delle Marche, Via Brecce Bianche, 60131 Ancona, Italy;3. Dipartimento di Ingegneria dell''informazione (DII), Facoltà di Ingegneria, Università Politecnica delle Marche, Via Brecce Bianche, 60131 Ancona, Italy;4. Dipartimento di Ingegneria Civile e dell’Architettura (DICEA), Facoltà di Ingegneria, Università Politecnica delle Marche, Via Brecce Bianche, 60131 Ancona, Italy |
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Abstract: | Pseudomonas sp. lipase was employed to resolve kinetically 1-O-alkylglycerols by a sequential diacylation process. Only low or moderate E-values were obtained, but at approximately 60% conversion enantiomerically pure monoacetates were obtained of the natural S-configuration for glyceryl ether lipids. |
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