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On the easy oxidation of (R)-2-[N-(1-phenylethyl)amino]-1-cyclopentenedithiocarboxylic acid to its disulfide dimer
Institution:1. School of Materials Science & Engineering, UNSW Sydney, NSW 2052, Australia;2. The University of Sydney. Australian Centre for Microscopy & Microanalysis, and School of Aerospace, Mechanical and Mechatronic Engineering, The University of Sydney, NSW 2006, Australia;3. voestalpine BÖHLER Aerospace GmbH & Co KG, Kapfenberg, Austria;1. Istituto di Ricerche sulla Combustione, CNR, P.le Tecchio 80, 80125 Napoli, Italy;2. IBM Research − Zurich, Säumerstrasse 4, 8803 Rüschlikon, Switzerland;3. Dipartimento di Ingegneria Chimica, dei Materiali e della Produzione Industriale, Università degli Studi di Napoli Federico II, P.le Tecchio 80, 80125 Napoli, Italy
Abstract:The physical and spectroscopic data of (R)-2-N-(1-phenylethyl)amino]-1-cyclopentenedithiocarboxylic acid are reviewed and the synthesis of (R)-di-2-(N-(1-phenylethyl)amino]-1-cyclopentenedithiocarboxylic acid disulfide is described. The product resulting from the conjugate addition of the dithioacid to 2(5H)-furanone is also characterised.
Keywords:
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