A new chiral iminophosphine ligand derived from (1S,4S)-fenchone in palladium-catalyzed asymmetric allylic alkylations |
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| Affiliation: | 1. Department of Food, Environmental and Nutritional Sciences – DeFENS, University of Milan, via Mangiagalli 25, 20133 Milano, Italy;2. Department of Pharmaceutical Sciences – DISFARM, University of Milan, via Mangiagalli 25, 20133 Milano, Italy;1. Inonu University, Faculty of Arts and Sciences, Department of Chemistry, 44280 Malatya, Turkey;2. Agri Ibrahim Cecen University, Central Research and Application Laboratory, 04100 Agri, Turkey;3. Ataturk University, Faculty of Science, Department of Chemistry, 25240 Erzurum, Turkey;4. Inonu University, Vocational School of Health Service, 44280 Malatya, Turkey;5. Department of Biotechnology, Faculty of Science, Bartin University, 74100 Bartin, Turkey;1. Liaoning Key Laboratory of Lignocellulose Chemistry and BioMaterials, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian, 116034, China;2. Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China;3. School of Chemical Engineering & Advanced Materials, The University of Adelaide, Adelaide, SA, 5005, Australia;4. College of Energy, Xiamen University, Xiamen, 361005, China;5. State Key Lab of Physical Chemistry of Solid Surface, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China;1. College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Soochow University, Suzhou, Jiangsu, 215006, China;2. Department of Chemistry, Chemical Engineering Division, Technische Universität Berlin, Berlin, 10623, Germany |
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| Abstract: | A new chiral iminophosphine ligand derived from (1S,4S)-fenchone has been developed, and its usefulness as a chiral ligand in asymmetric synthesis was demonstrated in palladium-catalyzed allylic alkylations. |
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