Organocatalytic deprotonative functionalization of C(sp(2))-H and C(sp(3))-H bonds using in situ generated onium amide bases |
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| Authors: | Kiyofumi Inamoto Hitomi Okawa Hiroshi Taneda Maomi Sato Yutaro Hirono Misato Yonemoto Shoko Kikkawa Yoshinori Kondo |
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| Institution: | Graduate School of Pharmaceutical Sciences, Tohoku University, 6-3, Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan. inamoto@m.tohoku.ac.jp ykondo@m.tohoku.ac.jp. |
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| Abstract: | Onium amides, generated in situ from the combination of aminosilanes and onium fluorides (R(4)PF, R(4)NF), are employed for the first time as bases for catalytic deprotonative functionalization of C(sp(2))-H and activated C(sp(3))-H bonds under mild conditions. |
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