Metal catalyzed C(sp(3))-H bond amination of 2-alkyl azaarenes with diethyl azodicarboxylate |
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| Authors: | Jin-Ying Liu Hong-Ying Niu Shan Wu Gui-Rong Qu Hai-Ming Guo |
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| Institution: | College of Chemistry and Environmental Science, Key Laboratory of Green Chemical Media and Reactions of Ministry of Education, Henan Normal University, Xinxiang 453007, Henan, China. quguir@sina.com guohm518@hotmail.com. |
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| Abstract: | Metal-catalyzed direct C(sp(3))-H bond amination of 2-alkyl azaarenes with Ndouble bond, length as m-dash]N double bonds has been developed, which expands the scope of C(sp(3))-H bond activation reactions and provides a new access to medicinally important azaarene derivatives. |
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