Anion coordination by metallamacrocycles: a cryptand-like cavity |
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| Authors: | Albert Escuer Jordi Esteban Mercè Font-Bardia |
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| Institution: | Departament de Química Inorgánica, Universitat de Barcelona, Av. Diagonal 645, 08028-Barcelona, Spain. albert.escuer@qi.ub.es. |
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| Abstract: | A {Ni(9)(N(3))(9)} metallamacrocycle is able to coordinate azide and halide anions in trigonal prismatic cavities by means of H-bond interactions. It provides an unprecedented example of a self-assembled cryptand-like cavity. |
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