Plutonium(iv) complexation by diglycolamide ligands-coordination chemistry insight into TODGA-based actinide separations |
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| Authors: | Sean D Reilly Andrew J Gaunt Brian L Scott Giuseppe Modolo Mudassir Iqbal Willem Verboom Mark J Sarsfield |
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| Affiliation: | Los Alamos National Laboratory, Los Alamos, NM 87545, USA. gaunt@lanl.gov. |
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| Abstract: | Complexation of Pu(iv) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1?:?3 homoleptic Pu(iv) complex with the nitrate anions forced into the outer coordination sphere. |
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